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Issue 2, 2017
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Diastereoselective synthesis of trifluoromethylated 1,3-dioxanes by intramolecular oxa-Michael reaction

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Abstract

A highly diastereoselective synthesis of trifluoromethylated 1,3-dioxanes is described. The reaction proceeds by an addition/oxa-Michael sequence and works efficiently under mild reaction conditions, with a good substrate scope and acceptable to good yields.

Graphical abstract: Diastereoselective synthesis of trifluoromethylated 1,3-dioxanes by intramolecular oxa-Michael reaction

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Article information


Submitted
26 Oct 2016
Accepted
23 Nov 2016
First published
23 Nov 2016

This article is Open Access

Org. Biomol. Chem., 2017,15, 301-305
Article type
Communication

Diastereoselective synthesis of trifluoromethylated 1,3-dioxanes by intramolecular oxa-Michael reaction

L. Becerra-Figueroa, E. Brun, M. Mathieson, L. J. Farrugia, C. Wilson, J. Prunet and D. Gamba-Sánchez, Org. Biomol. Chem., 2017, 15, 301
DOI: 10.1039/C6OB02333A

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