Issue 3, 2017
From the journal:

New Journal of Chemistry

Diversified magnetic behaviors of new nickel(ii) and copper(ii) azido coordination polymers templated by diethyl or triethyl amines†

Ying Zeng,a   Sui-Jun Liu, ORCID logo *b   Cai-Ming Liu,*c   Yong-Rong Xiea  and  Zi-Yi Du*a  

* Corresponding authors

a Key Laboratory of Jiangxi University for Functional Materials Chemistry, College of Chemistry and Chemical Engineering, Gannan Normal University, Ganzhou 341000, P. R. China
E-mail: ziyidu@gmail.com

b School of Metallurgy and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, P. R. China
E-mail: liusuijun147@163.com

c Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, P. R. China
E-mail: cmliu@iccas.ac.cn

Abstract

The reactions of NiII or CuII ions with N3− anions in the presence of templated diethyl or triethyl amines afford three new azido-bridged coordination polymers, namely, [Ni(N3)2(Deeda)] (1), (DeaH)[Cu3(N3)7] (2), and (TeaH)[Cu4(N3)9] (3), where Deeda, (DeaH)+ and (TeaH)+ represent N,N-diethylethane-1,2-diamine, diethylammonium and triethylammonium, respectively. Magnetic studies revealed that they exhibit metamagnetism, spin glass and canted ferromagnetism, respectively, induced by different coordination modes of the azide ligands.

Graphical abstract: Diversified magnetic behaviors of new nickel(ii) and copper(ii) azido coordination polymers templated by diethyl or triethyl amines

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Article information

DOI
https://doi.org/10.1039/C6NJ03268K
Article type
Paper
Submitted
19 Oct 2016
Accepted
22 Dec 2016
First published
22 Dec 2016

New J. Chem., 2017,41, 1212-1218

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Diversified magnetic behaviors of new nickel(II) and copper(II) azido coordination polymers templated by diethyl or triethyl amines

Y. Zeng, S. Liu, C. Liu, Y. Xie and Z. Du, New J. Chem., 2017, 41, 1212 DOI: 10.1039/C6NJ03268K

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