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Issue 2, 2017
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Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR

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Abstract

Using 5,6-dihydro-5,6-epoxy-1,10-phenanthroline as the ligand L, the X-ray crystal structure of [FeL3](ClO4)2·2H2O is determined. Its EPR and magnetic properties indicate entrapment of an MLCT state of the type Fe(III)–L˙.

Graphical abstract: Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR

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Article information


Submitted
12 Sep 2016
Accepted
21 Dec 2016
First published
21 Dec 2016

New J. Chem., 2017,41, 452-456
Article type
Letter

Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR

N. K. Shee, M. G. B. Drew and D. Datta, New J. Chem., 2017, 41, 452
DOI: 10.1039/C6NJ02874H

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