Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR

Nirmal K. Shee; Michael G. B. Drew; Dipankar Datta

doi:10.1039/C6NJ02874H

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Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR†

Nirmal K. Shee,^a Michael G. B. Drew^b and Dipankar Datta

*^a

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* Corresponding authors

^a Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Calcutta 700 032, India
E-mail: icdd@iacs.res.in

^b Department of Chemistry, University of Reading, Whiteknights, Reading RG6 6AD, UK

Abstract

Using 5,6-dihydro-5,6-epoxy-1,10-phenanthroline as the ligand L, the X-ray crystal structure of [FeL₃](ClO₄)₂·2H₂O is determined. Its EPR and magnetic properties indicate entrapment of an MLCT state of the type Fe(III)–L⁻˙.

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DOI: https://doi.org/10.1039/C6NJ02874H
Article type: Letter
Submitted: 12 Sep 2016
Accepted: 21 Dec 2016
First published: 21 Dec 2016

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New J. Chem., 2017,41, 452-456

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Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR

N. K. Shee, M. G. B. Drew and D. Datta, New J. Chem., 2017, 41, 452 DOI: 10.1039/C6NJ02874H

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New Journal of Chemistry

Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR†

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Isolation of a metal-to-ligand charge-transfer (MLCT) state of a tris 1,4-diimine complex of iron in the solid state: X-ray crystal structure and EPR

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