Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.

Issue 5, 2017
Previous Article Next Article

Beyond native block copolymer morphologies

Author affiliations


Block copolymers are a well-studied and canonical self-assembly paradigm. Despite active research, new methods are continually emerging that allow the formation of yet more diverse and complex morphologies. In this review, we analyze and comment on the state-of-the-art with respect to exploiting block copolymers in order to form ‘non-native’ morphologies; that is, structures that deviate from the bulk equilibrium morphologies observed in the simplest block copolymer systems. The range of reviewed strategies can be organized with respect to where the final structural information is encoded. Self-assembly involves intrinsic encoding within the molecules themselves, while external fields or templates can be used to externally encode a desired structure. Hybrid strategies, which exploit the responsiveness of self-assembly but control it through external forces or process history, are particularly promising.

Graphical abstract: Beyond native block copolymer morphologies

Back to tab navigation

Article information

01 Aug 2017
13 Sep 2017
First published
20 Sep 2017

Mol. Syst. Des. Eng., 2017,2, 518-538
Article type

Beyond native block copolymer morphologies

G. S. Doerk and K. G. Yager, Mol. Syst. Des. Eng., 2017, 2, 518
DOI: 10.1039/C7ME00069C

Social activity

Search articles by author