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Abstract | Cited by

A facile and efficient approach to phosphinic amides was developed from diarylphosphine oxides and amines via electrosynthesis. A variety of phosphinic amides were obtained in one step with good to excellent yields under mild and metal-free conditions. The corresponding mechanism was investigated.

Graphical abstract: Efficient electrosynthesis of phosphinic amides via oxidative cross-coupling between N–H/P–H

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