A recyclable AgI/OAc− catalytic system for the efficient synthesis of α-alkylidene cyclic carbonates: carbon dioxide conversion at atmospheric pressure

Ye Yuan; Yu Xie; Cheng Zeng; Dandan Song; Somboon Chaemchuen; Cheng Chen; Francis Verpoort

doi:10.1039/C7GC00276A

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

A recyclable AgI/OAc⁻ catalytic system for the efficient synthesis of α-alkylidene cyclic carbonates: carbon dioxide conversion at atmospheric pressure†

Ye Yuan,^ab Yu Xie,^a Cheng Zeng,^b Dandan Song,^b Somboon Chaemchuen,^a Cheng Chen*^a and Francis Verpoort

*^abcd

Author affiliations

* Corresponding authors

^a State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, PR China
E-mail: francis.verpoort@ghent.ac.kr

^b School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, PR China

^c National Research Tomsk Polytechnic University, Lenin Avenue 30, Tomsk 634050, Russian Federation

^d Ghent University Global Campus Songdo, 119 Songdomunhwa-Ro, Yeonsu-Gu, Incheon, Korea

Abstract

The cyclization of carbon dioxide and propargylic alcohols, especially challenging substrates, were efficiently catalyzed by a green and recyclable AgI/OAc⁻ system under atmospheric pressure, which is shown to be the most recyclable system with 20 recycle rounds and has the lowest loading among all the reported recyclable systems that work under atmospheric pressure.

Download options Please wait...

Supplementary files

Supplementary information PDF (2490K)

Article information

DOI: https://doi.org/10.1039/C7GC00276A
Article type: Communication
Submitted: 23 Jan 2017
Accepted: 13 Apr 2017
First published: 17 Apr 2017

Download Citation

Green Chem., 2017,19, 2936-2940

Permissions

Request permissions

A recyclable AgI/OAc⁻ catalytic system for the efficient synthesis of α-alkylidene cyclic carbonates: carbon dioxide conversion at atmospheric pressure

Y. Yuan, Y. Xie, C. Zeng, D. Song, S. Chaemchuen, C. Chen and F. Verpoort, Green Chem., 2017, 19, 2936 DOI: 10.1039/C7GC00276A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Green Chemistry