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Volume 201, 2017
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Harvesting the photoexcited holes on a photocatalytic proton reduction metal–organic framework

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Abstract

The highly porous titanium based metal–organic framework NH2-MIL-125(Ti) has recently attracted significant attention in the field of photocatalysis as a promising material for H+ reduction. This work reveals charge transfer upon visible light illumination from this MOF to two different charge acceptors, as an alternative to sacrificial electron donors. Charge transfer is demonstrated through a combined spectroscopic study between this MOF and: (1) 2-(1H-pyrazol-3-yl)phenol, a molecule that functionally mimics the tyrosine–histidine pair, responsible for shuttling the holes to the oxygen evolving centre in natural photosynthesis, and (2) TEMPO, a well known and stable radical. Charge transfer of the holes from the MOF to these occluded molecules takes place on the picosecond time scale. This work suggests that, by coupling a stable and recyclable charge acceptor to the photogenerated holes, the charges can be utilised for oxidation reactions and, thus, link the reduction to the oxidation reactions in water splitting.

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Submitted
20 Jan 2017
Accepted
14 Mar 2017
First published
14 Mar 2017

This article is Open Access

Faraday Discuss., 2017,201, 71-86
Article type
Paper

Harvesting the photoexcited holes on a photocatalytic proton reduction metal–organic framework

J. G. Santaclara, A. I. Olivos-Suarez, I. du Fossé, A. Houtepen, J. Hunger, F. Kapteijn, J. Gascon and M. A. van der Veen, Faraday Discuss., 2017, 201, 71
DOI: 10.1039/C7FD00029D

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