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Issue 1, 2017
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Co3O4–C3N4 p–n nano-heterojunctions for the simultaneous degradation of a mixture of pollutants under solar irradiation

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Abstract

Environmental remediation employing sunlight-active semiconductor nano-heterostructures provides effective solutions for handling emerging contaminants through a greener approach. Herein, we report the creation of ultrafine dispersions of Co3O4 nanoparticles in a g-C3N4 matrix by a simple one-pot synthetic strategy involving the co-pyrolysis of constituent raw materials. Calcination of a homogeneous mixture of melamine and cobalt nitrate at 550 °C/2 h leads to the formation of Co3O4–C3N4 p–n nano-heterojunctions that displayed extended absorption in the visible wavelength region owing to the synergistic role of Co3O4 particles. Moreover, the surface area values of the composites reached 90 m2 g−1, a tenfold increase from the value of 8 m2 g−1 obtained for the pristine C3N4. The band bending, induced by the p–n nano-heterojunctions, leads to the formation of intimate interfaces having enhanced photophysical properties. The mass normalized photoluminescence spectra of the heterojunctions indicated reduced exciton recombinations that are validated further by the enhanced sunlight-induced photocatalytic degradation of a mixture of methylene blue and tetracycline organic pollutants.

Graphical abstract: Co3O4–C3N4 p–n nano-heterojunctions for the simultaneous degradation of a mixture of pollutants under solar irradiation

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Publication details

The article was received on 18 Sep 2016, accepted on 04 Nov 2016 and first published on 07 Nov 2016


Article type: Paper
DOI: 10.1039/C6EN00410E
Citation: Environ. Sci.: Nano, 2017,4, 212-221

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    Co3O4–C3N4 p–n nano-heterojunctions for the simultaneous degradation of a mixture of pollutants under solar irradiation

    P. Suyana, P. Ganguly, B. N. Nair, A. P. Mohamed, K. G. K. Warrier and U. S. Hareesh, Environ. Sci.: Nano, 2017, 4, 212
    DOI: 10.1039/C6EN00410E

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