Issue 3, 2018
From the journal:

Dalton Transactions

A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects†

Miquel Navarro, ORCID logo a   Mo Li,b   Stefan Bernhard ORCID logo b  and  Martin Albrecht ORCID logo *a  

* Corresponding authors

a Department of Chemistry & Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland
E-mail: martin.albrecht@dcb.unibe.ch

b Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, PA 15213, USA
E-mail: bern@cmu.edu

Abstract

A mesoinic pyridylideneamide ligand (PYA) was synthetized and fully characterized and coordinated to an iridium(III) center. This ligand represents the first example of a mesoionic N-donor ligand. Structural and spectroscopic analysis revealed unique properties which were exploited in chemically driven water oxidation catalysis.

Graphical abstract: A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects

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Article information

DOI
https://doi.org/10.1039/C7DT04555G
Article type
Communication
Submitted
03 Dec 2017
Accepted
06 Dec 2017
First published
06 Dec 2017

Dalton Trans., 2018,47, 659-662

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A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects

M. Navarro, M. Li, S. Bernhard and M. Albrecht, Dalton Trans., 2018, 47, 659 DOI: 10.1039/C7DT04555G

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