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Issue 3, 2018
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A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects

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Abstract

A mesoinic pyridylideneamide ligand (PYA) was synthetized and fully characterized and coordinated to an iridium(III) center. This ligand represents the first example of a mesoionic N-donor ligand. Structural and spectroscopic analysis revealed unique properties which were exploited in chemically driven water oxidation catalysis.

Graphical abstract: A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects

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Article information


Submitted
03 Dec 2017
Accepted
06 Dec 2017
First published
06 Dec 2017

Dalton Trans., 2018,47, 659-662
Article type
Communication

A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects

M. Navarro, M. Li, S. Bernhard and M. Albrecht, Dalton Trans., 2018, 47, 659
DOI: 10.1039/C7DT04555G

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