Issue 46, 2017

Magneto-structural correlation of hexakis-dmso cobalt(ii) complex

Abstract

The magnetostructural correlation of the hexakis-dmso cobalt(II) complex, [Co(dmso)6](BPh4)2 (dmso: dimethylsulfoxide), was investigated by single-crystal X-ray diffraction study and magnetic measurements. The magnetic analysis concluded the negative Δ value (H = Δ(L2z − 2/3) + E(L2xL2y) − (3/2)κλL·S + β[−(3/2)κLu + geSuHu (u = x, y, z)), and this was explained by the tetragonal elongation of the octahedral geometry. The magnetostructural correlation was ascertained by both the angular overlap model calculation and the density functional theory calculation.

Graphical abstract: Magneto-structural correlation of hexakis-dmso cobalt(ii) complex

Supplementary files

Article information

Article type
Paper
Submitted
04 Sep 2017
Accepted
31 Oct 2017
First published
31 Oct 2017

Dalton Trans., 2017,46, 16306-16314

Magneto-structural correlation of hexakis-dmso cobalt(II) complex

H. Sakiyama, R. Sudo, T. Abiko, D. Yoshioka, R. Mitsuhashi, M. Omote, M. Mikuriya, M. Yoshitake and M. Koikawa, Dalton Trans., 2017, 46, 16306 DOI: 10.1039/C7DT03269B

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