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Issue 43, 2017
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Metal fluoride nanotubes featuring square-planar building blocks in a high-pressure polymorph of AgF2

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Abstract

At a pressure of ca. 15 GPa, AgF2 transforms to an unprecedented orthorhombic polymorph featuring an array of tubular subunits which are built of corner sharing [AgF4] squares. This seems to be the first type of a metal fluoride nanowire and also the only one showing rigid square planar rather than common hexagonal or octahedral moieties.

Graphical abstract: Metal fluoride nanotubes featuring square-planar building blocks in a high-pressure polymorph of AgF2

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Article information


Submitted
28 Aug 2017
Accepted
23 Sep 2017
First published
16 Oct 2017

Dalton Trans., 2017,46, 14742-14745
Article type
Communication

Metal fluoride nanotubes featuring square-planar building blocks in a high-pressure polymorph of AgF2

A. Grzelak, J. Gawraczyński, T. Jaroń, D. Kurzydłowski, Z. Mazej, P. J. Leszczyński, V. B. Prakapenka, M. Derzsi, V. V. Struzhkin and W. Grochala, Dalton Trans., 2017, 46, 14742
DOI: 10.1039/C7DT03178E

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