Issue 33, 2017
From the journal:

Dalton Transactions

A mononuclear Co(ii) complex formed from pyridinedimethanol with manifold slow relaxation channels†

Dušan Valigura, ORCID logo a   Cyril Rajnák,a   Ján Moncol,b   Ján Titiša  and  Roman Boča ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Faculty of Natural Sciences, University of SS Cyril and Methodius, 91701 Trnava, Slovakia

b Institute of Inorganic Chemistry, FCHPT, Slovak University of Technology, 812 37 Bratislava, Slovakia

Abstract

A mononuclear hexacoordinate complex [Co(pydm)2](dnbz)2 formed from 2,6-pyridinedimethanol in the coordination sphere of Co(II) and dinitrobenzoato anions exhibits magnetic anisotropy of an easy axis type and a field induced slow magnetic relaxation with manifold relaxation channels. The low-frequency relaxation time is as slow as τLF = 0.13 s at BDC = 0.4 T and T = 1.9 K.

Graphical abstract: A mononuclear Co(ii) complex formed from pyridinedimethanol with manifold slow relaxation channels

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Article information

DOI
https://doi.org/10.1039/C7DT02131C
Article type
Paper
Submitted
12 Jun 2017
Accepted
20 Jul 2017
First published
20 Jul 2017

Dalton Trans., 2017,46, 10950-10956

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A mononuclear Co(II) complex formed from pyridinedimethanol with manifold slow relaxation channels

D. Valigura, C. Rajnák, J. Moncol, J. Titiš and R. Boča, Dalton Trans., 2017, 46, 10950 DOI: 10.1039/C7DT02131C

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