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Issue 31, 2017
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Chiral two bladed ML2 metallamacrocycles: design, structures and solution behavior

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Abstract

Chiral two bladed complexes of [Co(L)2][BF4]2 (1) and [Zn(L)2][BF4]2 (2) containing an atropoisomeric semi-rigid bidentate ligand L were synthesized and characterized. They are obtained as homochiral species but in a racemic mixture via a ligand self-sorting mechanism. These enantiomers can be differentiated in solution using optically active anions.

Graphical abstract: Chiral two bladed ML2 metallamacrocycles: design, structures and solution behavior

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Article information


Submitted
30 Mar 2017
Accepted
04 Jul 2017
First published
21 Jul 2017

Dalton Trans., 2017,46, 10240-10245
Article type
Paper

Chiral two bladed ML2 metallamacrocycles: design, structures and solution behavior

H. Soudry, C. Desmarets, G. Gontard, T. Edgington, A. L. Cooksy and H. Amouri, Dalton Trans., 2017, 46, 10240
DOI: 10.1039/C7DT01151B

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