Issue 20, 2017
From the journal:

Dalton Transactions

First examples of tri- and tetraphosphametacyclophanes: synthesis and isolation of an unusual hexapalladium complex containing pincer units with Pd–P covalent bonds†

Vitthalrao S. Kashid,a   Latchupatula Radhakrishnaa  and  Maravanji S. Balakrishna ORCID logo *a  

* Corresponding authors

a Phosphorus Laboratory, Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400 076, India
E-mail: krishna@chem.iitb.ac.in, msb_krishna@iitb.ac.in
Fax: +91-22-2576-7152
Tel: +91-22-2576-7181

Abstract

The synthesis of the first examples of tri- and tetraphosphametacyclophanes [m-{–C(O)C5H3N(C(O)PPh)}3 (1) and m-{–C(O)C5H3N(C(O)PPh)}4 (2)] is described. The reaction of 1 with [Pd(η3-C3H5)Cl]2 yielded a rare hexapalladium(II) complex with four Pd–P covalent bonds.

Graphical abstract: First examples of tri- and tetraphosphametacyclophanes: synthesis and isolation of an unusual hexapalladium complex containing pincer units with Pd–P covalent bonds

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Article information

DOI
https://doi.org/10.1039/C7DT00737J
Article type
Communication
Submitted
28 Feb 2017
Accepted
20 Apr 2017
First published
21 Apr 2017

Dalton Trans., 2017,46, 6510-6513

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First examples of tri- and tetraphosphametacyclophanes: synthesis and isolation of an unusual hexapalladium complex containing pincer units with Pd–P covalent bonds

V. S. Kashid, L. Radhakrishna and M. S. Balakrishna, Dalton Trans., 2017, 46, 6510 DOI: 10.1039/C7DT00737J

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