Probing the local structure of Prussian blue electrodes by 113Cd NMR spectroscopy

A. Flambard; A. Sugahara; S. De; M. Okubo; A. Yamada; R. Lescouëzec

doi:10.1039/C7DT00728K

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Probing the local structure of Prussian blue electrodes by ¹¹³Cd NMR spectroscopy†

A. Flambard,^a A. Sugahara,^b S. De,^a M. Okubo,^b A. Yamada^b and R. Lescouëzec

*^a

Author affiliations

* Corresponding authors

^a Sorbonne Universités, UPMC Paris 6, Institut Parisien de Chimie Moléculaire, CNRS UMR 8232, 4 place Jussieu, Paris 75252, France
E-mail: rodrigue.lescouezec@upmc.fr

^b Department of Chemical System Engineering, School of Engineering, The University of Tokyo, Hongo 7-3-1, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract

We demonstrate that ¹¹³Cd NMR is a potent technique to monitor the local electronic and structural states of the Prussian blue electrode during Li⁺ intercalation, providing an atomic-scale insight into the reaction mechanism.

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Article information

DOI: https://doi.org/10.1039/C7DT00728K
Article type: Communication
Submitted: 27 Feb 2017
Accepted: 31 Mar 2017
First published: 31 Mar 2017

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Dalton Trans., 2017,46, 6159-6162

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Probing the local structure of Prussian blue electrodes by ¹¹³Cd NMR spectroscopy

A. Flambard, A. Sugahara, S. De, M. Okubo, A. Yamada and R. Lescouëzec, Dalton Trans., 2017, 46, 6159 DOI: 10.1039/C7DT00728K

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Dalton Transactions