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Issue 11, 2017
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Tetradecanuclearity in 3d–4f chemistry: relaxation and magnetocaloric effects in [Ni II6Ln III8] species

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Abstract

The employment of 2-amino-isobutyric acid, Haib, and 2-hydroxy-1-naphthaldehyde, Hnaphth, in NiII/LnIII chemistry has led to the isolation and characterization of two new isostructural 3d–4f tetradecanuclear [NiII6LnIII8] clusters (Ln = GdIII, DyIII), with the Dy analogue displaying temperature and frequency dependent out-of-phase signals, and the Gd analogue showing interesting magnetocaloric properties.

Graphical abstract: Tetradecanuclearity in 3d–4f chemistry: relaxation and magnetocaloric effects in [NiII6LnIII8] species

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Article information


Submitted
11 Jan 2017
Accepted
08 Feb 2017
First published
09 Feb 2017

Dalton Trans., 2017,46, 3449-3452
Article type
Communication

Tetradecanuclearity in 3d–4f chemistry: relaxation and magnetocaloric effects in [NiII6LnIII8] species

A. B. Canaj, D. A. Kalofolias, M. Siczek, T. Lis, R. McNab, G. Lorusso, R. Inglis, M. Evangelisti and C. J. Milios, Dalton Trans., 2017, 46, 3449
DOI: 10.1039/C7DT00102A

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