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Issue 1, 2017
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A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te)

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Abstract

The first tellurocarbonyl complex with a half-sandwich structure [CpRuCl(CTe)(H2IMes)] was synthesized by a ligand substitution reaction. The practically complete series of the CpCE complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te) were systematically explored. The tellurium atom in the CTe complex could be smoothly replaced with lighter chalcogen atoms.

Graphical abstract: A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te)

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Article information


Submitted
23 Nov 2016
Accepted
24 Nov 2016
First published
24 Nov 2016

Dalton Trans., 2017,46, 44-48
Article type
Communication

A ruthenium tellurocarbonyl (CTe) complex with a cyclopentadienyl ligand: systematic studies of a series of chalcogenocarbonyl complexes [CpRuCl(CE)(H2IMes)] (E = O, S, Se, Te)

A. Suzuki, T. Arai, K. Ikenaga, Y. Mutoh, N. Tsuchida, S. Saito and Y. Ishii, Dalton Trans., 2017, 46, 44
DOI: 10.1039/C6DT04440A

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