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Issue 3, 2017
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Phosphine–imine and –enamido ligands for acceptorless dehydrogenation catalysis

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Abstract

A highly tunable phosphine–imine ligand family is introduced. Following metallation with ruthenium, deprotonation of the ligand affords a phosphine–enamido species. Complexes with the ligand in both the imine and enamido forms are active toward acceptorless dehydrogenation reactions.

Graphical abstract: Phosphine–imine and –enamido ligands for acceptorless dehydrogenation catalysis

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Publication details

The article was received on 24 Oct 2016, accepted on 22 Nov 2016 and first published on 28 Nov 2016


Article type: Communication
DOI: 10.1039/C6DT04088H
Dalton Trans., 2017,46, 647-650

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    Phosphine–imine and –enamido ligands for acceptorless dehydrogenation catalysis

    J. M. Stubbs, K. F. Firth, B. J. Bridge, K. J. Berger, R. J. Hazlehurst, P. D. Boyle and J. M. Blacquiere, Dalton Trans., 2017, 46, 647
    DOI: 10.1039/C6DT04088H

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