C–H⋯Cl− hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands

Mari Ikeda; Ajay Kumar Sah; Miki Iwase; Rina Murashige; Jun-ichi Ishi-i; Masatoshi Hasegawa; Chihiro Kachi-Terajima; Ki-Min Park; Shunsuke Kuwahara; Yoichi Habata

doi:10.1039/C6DT03390C

C–H⋯Cl⁻ hydrogen bonds in solution and in the solid-state: HgCl₂ complexes with cyclen-based cryptands†

Mari Ikeda,*^a Ajay Kumar Sah,^b Miki Iwase,^c Rina Murashige,^c Jun-ichi Ishi-i,^cd Masatoshi Hasegawa,^cd Chihiro Kachi-Terajima,^cd Ki-Min Park,^e Shunsuke Kuwahara^cd and Yoichi Habata

*^cd

Author affiliations

* Corresponding authors

^a Education Centre, Faculty of Engineering, Chiba Institute of Technology, 2-1-1 Shibazono, Narashino, Chiba 275-0023, Japan

^b Department of Chemistry, Birla Institute of Technology and Science, Pilani-333031, Rajasthan, India

^c Department of Chemistry, Faculty of Science, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan

^d Research Centre for Materials with Integrated Properties, Toho University, 2-2-1 Miyama, Funabashi, Chiba 274-8510, Japan
E-mail: habata@chem.sci.toho-u.ac.jp
Fax: +81 47 472 4322

^e Research Institute of Natural Science, Gyeongsang National University, Jinju, South Korea

Abstract

Structural evidence is reported for C–H⋯Cl⁻ hydrogen bonds in solution and in the solid state of HgCl₂ complexes with cyclen-based cryptands. These cyclen-based cryptands (1) and (2) are bridged by di- and triethylene glycol units, respectively, between two aromatic rings. The X-ray structure indicates that the 2/HgCl₂ complex contains an acetonitrile molecule in the cavity.

Dalton Transactions

C–H⋯Cl⁻ hydrogen bonds in solution and in the solid-state: HgCl₂ complexes with cyclen-based cryptands†

Abstract

Supplementary files

Article information

Download Citation

Permissions

C–H⋯Cl⁻ hydrogen bonds in solution and in the solid-state: HgCl₂ complexes with cyclen-based cryptands

Social activity

Search articles by author

Spotlight

Advertisements

Dalton Transactions