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Issue 24, 2017
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Iridium(iii)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

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Abstract

Cyclometallated iridium(III) complexes with 2-phenylpyridine [Ir(ppy)2(CNR)Cl] (ppy = (2-phenylpyridinato-C2,N), R = Xyl, Mes), [Ir(ppy)2(CNR)2](OTf) (R = Xyl, Mes), and fac-[Ir(ppy)3] catalyse the cross-linking of polysiloxanes exclusively at temperatures above 100 °C leading to luminescent rubbers.

Graphical abstract: Iridium(iii)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

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Supplementary files

Article information


Submitted
30 Sep 2017
Accepted
01 Nov 2017
First published
01 Nov 2017

This article is Open Access

Catal. Sci. Technol., 2017,7, 5843-5846
Article type
Communication

Iridium(III)-catalysed cross-linking of polysiloxanes leading to the thermally resistant luminescent silicone rubbers

R. M. Islamova, M. V. Dobrynin, A. V. Vlasov, A. A. Eremina, M. A. Kinzhalov, I. E. Kolesnikov, A. A. Zolotarev, E. A. Masloborodova and K. V. Luzyanin, Catal. Sci. Technol., 2017, 7, 5843
DOI: 10.1039/C7CY02013A

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