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Issue 23, 2017
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Elucidating the role of oxygen coverage in CO2 reduction on Mo2C

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Abstract

Molybdenum carbide (Mo2C) is a promising and low-cost catalyst for the conversion of CO2 to CO. However, the underpinning mechanism occurring on the catalyst surface and the understanding of the catalyst structure under the reaction conditions is still elusive. In this study, we employ first principles calculations to understand the CO2 dissociation mechanism on β-Mo2C (001) under different oxygen coverage on the catalyst surface (oxycarbide). Our results demonstrate that with increasing oxygen coverage, there is an electronic modification on the catalyst surface (e.g. d-band shift on Mo atoms), that in turn, tunes the interactions of the adsorbates and the CO2 dissociation barriers. Interestingly, we reveal linear relationships between the oxygen coverage and electronic modification with the reactivity of the catalyst. We show that CO2 can adsorb and dissociate on the oxygen covered Mo2C surface, even in the presence of surface oxygen up to 0.5 monolayer (ML). Our results rationalize a series of experimental observations.

Graphical abstract: Elucidating the role of oxygen coverage in CO2 reduction on Mo2C

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Supplementary files

Article information


Submitted
01 Sep 2017
Accepted
09 Oct 2017
First published
10 Oct 2017

Catal. Sci. Technol., 2017,7, 5521-5529
Article type
Paper

Elucidating the role of oxygen coverage in CO2 reduction on Mo2C

M. Dixit, X. Peng, M. D. Porosoff, H. D. Willauer and G. Mpourmpakis, Catal. Sci. Technol., 2017, 7, 5521
DOI: 10.1039/C7CY01810J

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