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Issue 15, 2017
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Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(ii) and its derivatives

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Abstract

Simple nickel salts, bis(acetylacetonato)nickel(II) and its derivatives, catalysed the hydroboration reactions of aryl and alkyl nitriles with catechol borane. The reaction smoothly proceeded for nitriles with various substituents to form the corresponding bis(boryl)amines in good to excellent yields.

Graphical abstract: Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(ii) and its derivatives

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Submitted
12 May 2017
Accepted
29 May 2017
First published
30 May 2017

Catal. Sci. Technol., 2017,7, 3196-3199
Article type
Communication

Nitrile hydroboration reactions catalysed by simple nickel salts, bis(acetylacetonato)nickel(II) and its derivatives

G. Nakamura, Y. Nakajima, K. Matsumoto, V. Srinivas and S. Shimada, Catal. Sci. Technol., 2017, 7, 3196
DOI: 10.1039/C7CY00944E

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