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Issue 43, 2017
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Long-range magnetic order in the porous metal–organic framework Ni(pyrazine)[Pt(CN)4]

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Abstract

A combined study involving DFT calculations, neutron scattering, heat capacity and magnetic measurements at very low temperatures demonstrates the long-range magnetic ordering of Ni(pyrazine)[Pt(CN)4] below 1.9 K, describing its antiferromagnetic spin arrangement. This compound belongs to the family of porous coordination polymers M(pyrazine)[Pt(CN)4] (M = divalent metal), renowned for showing interesting combinations of porosity and magnetic properties. The possibility of including long-range magnetic ordering, one of the most pursued functional properties, opens new perspectives for the multifunctionality of this class of compounds.

Graphical abstract: Long-range magnetic order in the porous metal–organic framework Ni(pyrazine)[Pt(CN)4]

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Publication details

The article was received on 14 Sep 2017, accepted on 16 Oct 2017 and first published on 16 Oct 2017


Article type: Paper
DOI: 10.1039/C7CP06310E
Citation: Phys. Chem. Chem. Phys., 2017,19, 29084-29091
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    Long-range magnetic order in the porous metal–organic framework Ni(pyrazine)[Pt(CN)4]

    J. A. Rodríguez-Velamazán, O. Roubeau, R. Poloni, E. Lhotel, E. Palacios, M. A. González and J. A. Real, Phys. Chem. Chem. Phys., 2017, 19, 29084
    DOI: 10.1039/C7CP06310E

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