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Issue 41, 2017
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Structural rationale for the chiral separation and migration order reversal of clenpenterol enantiomers in capillary electrophoresis using two different β-cyclodextrins

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Abstract

NMR spectroscopy experiments, molecular dynamics simulations, and theoretical chemistry calculations provide insight into the structural and energetic determinants of the distinct binding of clenpenterol enantiomers to two cyclodextrins and the migration order reversal of their respective inclusion complexes in capillary electrophoresis.

Graphical abstract: Structural rationale for the chiral separation and migration order reversal of clenpenterol enantiomers in capillary electrophoresis using two different β-cyclodextrins

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Article information


Submitted
14 Jul 2017
Accepted
27 Sep 2017
First published
27 Sep 2017

Phys. Chem. Chem. Phys., 2017,19, 27935-27939
Article type
Communication

Structural rationale for the chiral separation and migration order reversal of clenpenterol enantiomers in capillary electrophoresis using two different β-cyclodextrins

A. Salgado, E. Tatunashvili, A. Gogolashvili, B. Chankvetadze and F. Gago, Phys. Chem. Chem. Phys., 2017, 19, 27935
DOI: 10.1039/C7CP04761D

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