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Issue 42, 2017
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Salt-induced thermochromism of a conjugated polyelectrolyte

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Abstract

We report here the photophysical properties of a water-soluble conjugated polythiophene with cationic side-chains. When dissolved in aqueous buffer solution (PBS, phosphate buffered saline), there is ordering of the polymer chains due to the presence of the salts, in contrast to pure water, where a random-coil conformation is adopted at room temperature. The ordering leads to a pronounced colour change of the solution (the absorption maximum shifts from 400 nm to 525 nm). Combining resonance Raman spectroscopy with density functional theory computations, we show a significant backbone planarization in the ordered phase. Moreover, the ratio of ordered phase to random-coil phase in PBS solution, as well as the extent of intermolecular interactions in the ordered phase, can be tuned by varying the temperature. Femtosecond transient absorption spectroscopy reveals that the excited-state behaviour of the polyelectrolyte is strongly affected by the degree of ordering. While triplet state formation is favoured in the random-coil chains, the ordered chains show a weak yield of polarons, related to interchain interactions. The investigated polyelectrolyte has been previously used as a biological DNA sensor, based on optical transduction when the conformation of the polyelectrolyte changes during assembly with the biomolecule. Therefore, our results, by correlating the photophysical properties of the polyelectrolyte to backbone and intermolecular conformation in a biologically relevant buffer, provide a significant step forward in understanding the mechanism of the biological sensing.

Graphical abstract: Salt-induced thermochromism of a conjugated polyelectrolyte

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Supplementary files

Article information


Submitted
26 Apr 2017
Accepted
10 Oct 2017
First published
10 Oct 2017

Phys. Chem. Chem. Phys., 2017,19, 28853-28866
Article type
Paper

Salt-induced thermochromism of a conjugated polyelectrolyte

L. Peterhans, E. Alloa, Y. Sheima, L. Vannay, M. Leclerc, C. Corminboeuf, S. C. Hayes and N. Banerji, Phys. Chem. Chem. Phys., 2017, 19, 28853
DOI: 10.1039/C7CP02734F

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