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Issue 34, 2017
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Tridentate C–I⋯O–N+ halogen bonds

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The X-ray structures of the first co-crystals where the three oxygen lone pairs in N-oxides are fully utilized for tridentate C–I⋯O–N+ halogen bonding with 1,ω-diiodoperfluoroalkanes are reported, studied computationally, and compared with the corresponding silver(I) N-oxide complexes.

Graphical abstract: Tridentate C–I⋯O−–N+ halogen bonds

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The article was received on 28 Jul 2017, accepted on 01 Aug 2017 and first published on 17 Aug 2017

Article type: Communication
DOI: 10.1039/C7CE01381G
CrystEngComm, 2017,19, 4960-4963

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    Tridentate C–I⋯O–N+ halogen bonds

    F. Topić, R. Puttreddy, J. M. Rautiainen, H. M. Tuononen and K. Rissanen, CrystEngComm, 2017, 19, 4960
    DOI: 10.1039/C7CE01381G

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