p-Selective (sp2)-C–H functionalization for an acylation/alkylation reaction using organic photoredox catalysis

Ganesh Pandey; Sandip Kumar Tiwari; Bhawana Singh; Kumar Vanka; Shailja Jain

doi:10.1039/C7CC07529D

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p-Selective (sp²)-C–H functionalization for an acylation/alkylation reaction using organic photoredox catalysis†

Ganesh Pandey,

*^a Sandip Kumar Tiwari,^a Bhawana Singh,^a Kumar Vanka^b and Shailja Jain^b

Author affiliations

* Corresponding authors

^a Molecular Synthesis and Drug Discovery Laboratory, Centre of Bio-Medical Research (CBMR), Sanjay Gandhi Postgraduate Institute of Medical Science Campus, Raebareli Road, Lucknow-226014, India
E-mail: gp.pandey@cbmr.res.in

^b Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory, Pune – 411008, India

Abstract

p-Selective (sp²)-C–H functionalization of electron rich arenes has been achieved for acylation and alkylation reactions, respectively, with acyl/alkylselenides by organic photoredox catalysis involving an interesting mechanistic pathway.

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Article information

DOI: https://doi.org/10.1039/C7CC07529D
Article type: Communication
Submitted: 27 Sep 2017
Accepted: 26 Oct 2017
First published: 26 Oct 2017

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Chem. Commun., 2017,53, 12337-12340

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p-Selective (sp²)-C–H functionalization for an acylation/alkylation reaction using organic photoredox catalysis

G. Pandey, S. K. Tiwari, B. Singh, K. Vanka and S. Jain, Chem. Commun., 2017, 53, 12337 DOI: 10.1039/C7CC07529D

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