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Issue 85, 2017
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Facile insertion of a cyclic alkyl(amino) carbene carbon into the B–B bond of diboron(4) reagents

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Abstract

We report herein the room temperature insertion of the carbene carbon atom of the cyclic (alkyl)(amino) carbene cAACMe into the B–B single bonds of the diboron(4) compounds B2pin2, B2cat2, B2neop2, and B2eg2 (pin = pinacolato, cat = catecholato, neop = neopentylglycolato, eg = ethyleneglycolato).

Graphical abstract: Facile insertion of a cyclic alkyl(amino) carbene carbon into the B–B bond of diboron(4) reagents

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Article information


Submitted
11 Aug 2017
Accepted
04 Oct 2017
First published
04 Oct 2017

Chem. Commun., 2017,53, 11694-11696
Article type
Communication

Facile insertion of a cyclic alkyl(amino) carbene carbon into the B–B bond of diboron(4) reagents

A. F. Eichhorn, L. Kuehn, T. B. Marder and U. Radius, Chem. Commun., 2017, 53, 11694
DOI: 10.1039/C7CC06302D

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