Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 27th March 2019 from 11:00 AM to 1:00 PM (GMT).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 75, 2017
Previous Article Next Article

Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes

Author affiliations

Abstract

The cyclohexa-1,3-diene motif is introduced as an equally effective alternative to the cyclohexa-1,4-diene platform in B(C6F5)3-catalysed transfer processes. The transfer hydrogenation of alkenes is realised with α-terpinene and the related transfer hydrosilylation is achieved with 5-trimethylsilyl-substituted cyclohexa-1,3-diene. Both yields and substrate scope are comparable with the prior systems.

Graphical abstract: Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes

Back to tab navigation

Supplementary files

Publication details

The article was received on 08 Aug 2017, accepted on 29 Aug 2017 and first published on 29 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC06195A
Citation: Chem. Commun., 2017,53, 10390-10393

  •   Request permissions

    Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes

    W. Yuan, P. Orecchia and M. Oestreich, Chem. Commun., 2017, 53, 10390
    DOI: 10.1039/C7CC06195A

Search articles by author

Spotlight

Advertisements