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Issue 75, 2017
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Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes

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Abstract

The cyclohexa-1,3-diene motif is introduced as an equally effective alternative to the cyclohexa-1,4-diene platform in B(C6F5)3-catalysed transfer processes. The transfer hydrogenation of alkenes is realised with α-terpinene and the related transfer hydrosilylation is achieved with 5-trimethylsilyl-substituted cyclohexa-1,3-diene. Both yields and substrate scope are comparable with the prior systems.

Graphical abstract: Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes

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Article information


Submitted
08 Aug 2017
Accepted
29 Aug 2017
First published
29 Aug 2017

Chem. Commun., 2017,53, 10390-10393
Article type
Communication

Cyclohexa-1,3-diene-based dihydrogen and hydrosilane surrogates in B(C6F5)3-catalysed transfer processes

W. Yuan, P. Orecchia and M. Oestreich, Chem. Commun., 2017, 53, 10390
DOI: 10.1039/C7CC06195A

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