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Abstract | Cited by

A highly stereoselective cyclopropanation of various olefins with diazosulfones catalyzed by chiral Ru(II)–Pheox complexes was developed to give chiral cyclopropyl sulfones in high yields (up to 99%) with excellent trans-selectivity and enantioselectivity (up to 98% ee).

Graphical abstract: Highly stereoselective cyclopropanation of various olefins with diazosulfones catalyzed by Ru(ii)–Pheox complexes

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