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Abstract | Cited by

The formation and spectroscopic characterization of a superoxido cobalt(III) and a peroxido dicobalt(III) species formed in the temperature dependent reversible reaction of a cobalt(II) precursor with O2 is described. The electronic nature of each species is explored in their reactivity with organic substrates.

Graphical abstract: Trapping of superoxido cobalt and peroxido dicobalt species formed reversibly from CoII and O2

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