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Visible light-mediated α-arylation of α,β-unsaturated imides is achieved via aminium radicals generated from diarylalkylamines using a photoredox catalyst. On the basis of emission quenching experiments, a plausible pathway of the reaction is discussed.

Graphical abstract: Selective α-arylation of α,β-unsaturated imides mediated by a visible light photoredox catalyst

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