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Issue 74, 2017
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Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network

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Abstract

The organization of a molecular FeIII complex embedded in a halogen-bonded 2D network is chemically tuned to trigger temperature- and light-induced spin-state switching. We attribute the associated magnetic properties and the unprecedented photoswitching effect to the optimized structural confinement provided by the presence of the supramolecular host framework.

Graphical abstract: Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network

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Supplementary files

Article information


Submitted
16 May 2017
Accepted
24 Aug 2017
First published
24 Aug 2017

Chem. Commun., 2017,53, 10283-10286
Article type
Communication

Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network

I. Jeon, C. Mathonière, R. Clérac, M. Rouzières, O. Jeannin, E. Trzop, E. Collet and M. Fourmigué, Chem. Commun., 2017, 53, 10283
DOI: 10.1039/C7CC03797J

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