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Issue 74, 2017
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Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network

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Abstract

The organization of a molecular FeIII complex embedded in a halogen-bonded 2D network is chemically tuned to trigger temperature- and light-induced spin-state switching. We attribute the associated magnetic properties and the unprecedented photoswitching effect to the optimized structural confinement provided by the presence of the supramolecular host framework.

Graphical abstract: Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network

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Publication details

The article was received on 16 May 2017, accepted on 24 Aug 2017 and first published on 24 Aug 2017


Article type: Communication
DOI: 10.1039/C7CC03797J
Chem. Commun., 2017,53, 10283-10286

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    Photoinduced reversible spin-state switching of an FeIII complex assisted by a halogen-bonded supramolecular network

    I. Jeon, C. Mathonière, R. Clérac, M. Rouzières, O. Jeannin, E. Trzop, E. Collet and M. Fourmigué, Chem. Commun., 2017, 53, 10283
    DOI: 10.1039/C7CC03797J

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