Issue 55, 2017
From the journal:

Chemical Communications

Thermal decomposition pathways of nitro-functionalized metal–organic frameworks†

Kyle A. McDonald, ORCID logo a   Nakeun Ko,b   Kyungkyou Noh,c   Jonathan C. Bennion, ORCID logo a   Jaheon Kim ORCID logo *bc  and  Adam J. Matzger ORCID logo *ad  

* Corresponding authors

a Department of Chemistry, University of Michigan, Ann Arbor, Michigan, USA
E-mail: matzger@umich.edu

b Department of Chemistry, Soongsil University, 511 Sangdo-Dong, Dongjak-Gu, Seoul, Republic of Korea
E-mail: jaheon@ssu.ac.kr

c Department of Information Communication, Materials, and Chemistry Convergence Technology, Soongsil University, 511 Sangdo-Dong, Dongjak-Gu, Seoul, Republic of Korea

d Macromolecular Science and Engineering, University of Michigan, Ann Arbor, Michigan, USA

Abstract

The decomposition behavior of high energy metal–organic frameworks (MOFs) with extensive nitration is disclosed. In contrast to the detonation behavior observed in molecular energetic compounds, deflagration transforms cubic MOFs into anisotropic carbon structures with highly dispersed metal. Both the structural metal and intimate mixing are found to be critical.

Graphical abstract: Thermal decomposition pathways of nitro-functionalized metal–organic frameworks

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Article information

DOI
https://doi.org/10.1039/C7CC03354K
Article type
Communication
Submitted
02 May 2017
Accepted
21 Jun 2017
First published
21 Jun 2017

Chem. Commun., 2017,53, 7808-7811

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Thermal decomposition pathways of nitro-functionalized metal–organic frameworks

K. A. McDonald, N. Ko, K. Noh, J. C. Bennion, J. Kim and A. J. Matzger, Chem. Commun., 2017, 53, 7808 DOI: 10.1039/C7CC03354K

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