Issue 54, 2017

Functionalised cyclodextrin-based metal–organic frameworks

Abstract

CD-MOF, an extended framework incorporating the C8 symmetric cyclic oligosaccharide, γ-cyclodextrin (γ-CD), is based on the coordination of alkali metal cations to alternating α-1,4-linked D-glucopyranosyl units on the primary and secondary faces of the γ-CD tori. Here, we report the synthesis and characterisation of an amino-functionalised CD-MOF that is isostructural with pristine CD-MOF and adsorbs CO2 permanently.

Graphical abstract: Functionalised cyclodextrin-based metal–organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
29 Apr 2017
Accepted
13 Jun 2017
First published
13 Jun 2017

Chem. Commun., 2017,53, 7561-7564

Functionalised cyclodextrin-based metal–organic frameworks

K. J. Hartlieb, A. W. Peters, T. C. Wang, P. Deria, O. K. Farha, J. T. Hupp and J. F. Stoddart, Chem. Commun., 2017, 53, 7561 DOI: 10.1039/C7CC03345A

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