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Issue 57, 2017

A more critical role for silicon in the catalytic Staudinger amidation: silanes as non-innocent reductants

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Abstract

A revised pathway for the catalytic Staudinger amidation reaction is presented that involves the intervention of in situ-generated silyl esters as the species responsible for amidation.

Graphical abstract: A more critical role for silicon in the catalytic Staudinger amidation: silanes as non-innocent reductants

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Article information


Submitted
21 Apr 2017
Accepted
15 May 2017
First published
19 May 2017

Chem. Commun., 2017,53, 7982-7985
Article type
Communication

A more critical role for silicon in the catalytic Staudinger amidation: silanes as non-innocent reductants

K. G. Andrews and R. M. Denton, Chem. Commun., 2017, 53, 7982 DOI: 10.1039/C7CC03076B

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