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Issue 68, 2017
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Diastereoselective synthesis of novel heterocyclic scaffolds through tandem Petasis 3-component/intramolecular Diels–Alder and ROM–RCM reactions

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Abstract

A high-yielding, stereoselective and extraordinarily complexity-generating Petasis 3-component/intramolecular Diels–Alder reaction has been developed. In combination with ROM–RCM, rapid access to complex sp3-rich heterocyclic scaffolds amenable to subsequent functionalization and library synthesis is provided.

Graphical abstract: Diastereoselective synthesis of novel heterocyclic scaffolds through tandem Petasis 3-component/intramolecular Diels–Alder and ROM–RCM reactions

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Article information


Submitted
17 Apr 2017
Accepted
29 Jun 2017
First published
29 Jun 2017

Chem. Commun., 2017,53, 9410-9413
Article type
Communication

Diastereoselective synthesis of novel heterocyclic scaffolds through tandem Petasis 3-component/intramolecular Diels–Alder and ROM–RCM reactions

M. Ishoey, R. G. Petersen, M. Å. Petersen, P. Wu, M. H. Clausen and T. E. Nielsen, Chem. Commun., 2017, 53, 9410
DOI: 10.1039/C7CC02948A

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