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Issue 45, 2017
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N-Heterocyclic carbene-stabilised arsinidene (AsH)

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Abstract

N-Heterocyclic carbene adducts of the parent arsinidene (AsH) were prepared by two different synthetic routes, either by reaction of As(SiMe3)3 with 2,2-difluoroimidazolines followed by desilylation or by reaction of [Na(dioxane)3.31][AsCO] with imidazolium chlorides.

Graphical abstract: N-Heterocyclic carbene-stabilised arsinidene (AsH)

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Article information


Submitted
05 Apr 2017
Accepted
24 Apr 2017
First published
25 Apr 2017

Chem. Commun., 2017,53, 6069-6072
Article type
Communication

N-Heterocyclic carbene-stabilised arsinidene (AsH)

A. Doddi, M. Weinhart, A. Hinz, D. Bockfeld, J. M. Goicoechea, M. Scheer and M. Tamm, Chem. Commun., 2017, 53, 6069
DOI: 10.1039/C7CC02628E

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