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Abstract | Cited by

An apatite-type barium phosphate with a high content of cobalt ions in the trigonal channels features slow relaxation of magnetization with an energy barrier Ueff of up to 387 cm−1, which is well above the values for all so far known d-metal based single-molecule magnets (SMMs).

Graphical abstract: A Co-based single-molecule magnet confined in a barium phosphate apatite matrix with a high energy barrier for magnetization relaxation

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