A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons

Aya Yoshimura; Michiyo Yoshinaga; Hiroshi Yamashita; Masayasu Igarashi; Shigeru Shimada; Kazuhiko Sato

doi:10.1039/C7CC02420G

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A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons†

Aya Yoshimura,‡^a Michiyo Yoshinaga,^a Hiroshi Yamashita,

*^a Masayasu Igarashi,^a Shigeru Shimada

^a and Kazuhiko Sato^a

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* Corresponding authors

^a National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1, Higashi, Tsukuba, Ibaraki 305-8565, Japan
E-mail: hiro-yamashita@aist.go.jp

Abstract

Selective O-borylation of silanols with diborons took place in the presence of Pd catalysts to give the corresponding boryl silyl ethers in high yields.

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Article information

DOI: https://doi.org/10.1039/C7CC02420G
Article type: Communication
Submitted: 29 Mar 2017
Accepted: 03 May 2017
First published: 03 May 2017

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Chem. Commun., 2017,53, 5822-5825

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A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons

A. Yoshimura, M. Yoshinaga, H. Yamashita, M. Igarashi, S. Shimada and K. Sato, Chem. Commun., 2017, 53, 5822 DOI: 10.1039/C7CC02420G

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Chemical Communications

A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons†

Abstract

Supplementary files

Article information

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A convenient and clean synthetic method for borasiloxanes by Pd-catalysed reaction of silanols with diborons

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