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Issue 37, 2017
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Highly efficient Tsuji–Trost allylation in water catalyzed by Pd-nanoparticles

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Abstract

Palladium nanoparticles stabilized by poly(vinylpyrrolidone) catalyze Tsuji–Trost allylations in water with very high turnover numbers. The di-allylation of methylene active compounds and the allylation of bio-based phenols was performed in high yield. The allylation of lignin showed a high selectivity towards the phenolic OH groups.

Graphical abstract: Highly efficient Tsuji–Trost allylation in water catalyzed by Pd-nanoparticles

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Article information


Submitted
28 Mar 2017
Accepted
18 Apr 2017
First published
18 Apr 2017

Chem. Commun., 2017,53, 5175-5178
Article type
Communication

Highly efficient Tsuji–Trost allylation in water catalyzed by Pd-nanoparticles

A. Llevot, B. Monney, A. Sehlinger, S. Behrens and M. A. R. Meier, Chem. Commun., 2017, 53, 5175
DOI: 10.1039/C7CC02380D

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