Issue 33, 2017
From the journal:

Chemical Communications

Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance†‡

Sandeep Yadav,a   Sanjukta Pahara  and  Sakya S. Sen ORCID logo *a  

* Corresponding authors

a Inorganic Chemistry and Catalysis Division, CSIR-National Chemical Laboratory, Dr Homi Bhabha Road, Pashan, Pune 411008, India
E-mail: ss.sen@ncl.res.in

Abstract

A benz-amidinato calcium compound, [PhC(NiPr)2CaI] (1), catalyzed hydroboration of a wide range of aldehydes and ketones using pinacolborane (HBpin) at room temperature is reported. The catalyst shows functional group tolerance even towards OH and NH groups. The strategy was further extended to imines.

Graphical abstract: Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance

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Article information

DOI
https://doi.org/10.1039/C7CC02311A
Article type
Communication
Submitted
27 Mar 2017
Accepted
30 Mar 2017
First published
31 Mar 2017

Chem. Commun., 2017,53, 4562-4564

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Benz-amidinato calcium iodide catalyzed aldehyde and ketone hydroboration with unprecedented functional group tolerance

S. Yadav, S. Pahar and S. S. Sen, Chem. Commun., 2017, 53, 4562 DOI: 10.1039/C7CC02311A

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