Twofold hydroboration of the bulky Mes*P(vinyl)2 phosphane with Piers’ borane [HB(C6F5)2] followed by C6F5/H exchange with 9-BBN generated a reactive P/B/BH FLP structure that cleanly reduced carbon monoxide at the trifunctional frustrated Lewis pair framework to the [B]-formyl stage.
L. Wang, S. Zhang, Y. Hasegawa, C. G. Daniliuc, G. Kehr and G. Erker, Chem. Commun., 2017, 53, 5499 DOI: 10.1039/C7CC02214J
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