Issue 34, 2017
From the journal:

Chemical Communications

Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(ii) compounds†

Ryohei Akiyoshi,a   Keita Kuroiwa, ORCID logo b   Saliu Alao Amolegbe,ac   Manabu Nakaya,a   Ryo Ohtani, ORCID logo a   Masaaki Nakamura,a   Leonard F. Lindoyd  and  Shinya Hayami ORCID logo *ae  

* Corresponding authors

a Department of Chemistry, Graduate School of Science and Technology, Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan
E-mail: hayami@sci.kumamoto-u.ac.jp

b Department of Nanoscience, Faculty of Engineering, Sojo University, 4-22-1 Ikeda, Nishi-ku, Kumamoto 860-0082, Japan

c Department of Chemistry, College of Physical Science, Federal University of Agriculture, Abeokuta, Nigeria

d School of Chemistry, The University of Sydney, Australia

e Institute of Pulsed Power Science (IPPS), Kumamoto University, 2-39-1 Kurokami, Chuo-ku, Kumamoto 860-8555, Japan

Abstract

Self-assembled hybrid supramolecular architectures formed between amphiphilic anions and long alkylated cationic cobalt(II) complexes of type [Co(Cn-terpy)2](C12-Glu)2 (n = 15–20) have been synthesized and characterized by TEM, PXRD and magnetic susceptibility measurements. The hybrids display wire or rolled sheet supramolecular arrangements with odd and even alkyl chain dependence, with the cobalt(II) centres exhibiting gradual spin-crossover behaviours.

Graphical abstract: Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(ii) compounds

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Article information

DOI
https://doi.org/10.1039/C7CC01501A
Article type
Communication
Submitted
28 Feb 2017
Accepted
27 Mar 2017
First published
28 Mar 2017

Chem. Commun., 2017,53, 4685-4687

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Supramolecular architectures self-assembled using long chain alkylated spin crossover cobalt(II) compounds

R. Akiyoshi, K. Kuroiwa, S. Alao Amolegbe, M. Nakaya, R. Ohtani, M. Nakamura, L. F. Lindoy and S. Hayami, Chem. Commun., 2017, 53, 4685 DOI: 10.1039/C7CC01501A

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