Issue 37, 2017
From the journal:

Chemical Communications

Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions†

Sven H. Zottnick,a   Maik Finzea  and  Klaus Müller-Buschbaum ORCID logo *a  

* Corresponding authors

a Universität Würzburg, Institut für Anorganische Chemie, Am Hubland, 97074 Würzburg, Germany
E-mail: k.mueller-buschbaum@uni-wuerzburg.de
Fax: +49 931 3184785
Tel: +49 931 3188724

Abstract

The lanthanum tetracyanoborate coordination polymers [EMIM] 1∞[LaNO3{B(CN)4}3(H2O)3] (EMIM = 1-ethyl-3-methylimidazolium) and 1∞[La(NO3)2[B(CN)4](H2O)4] mark first examples of Ln-tetracyanoborates that have been obtained in ionothermal syntheses without further solvents to influence e.g. viscosity. Thereby, the ionic liquid [EMIM][B(CN)4] is fully incorporated into product formation.

Graphical abstract: Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions

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Article information

DOI
https://doi.org/10.1039/C7CC01378G
Article type
Communication
Submitted
21 Feb 2017
Accepted
19 Apr 2017
First published
20 Apr 2017

Chem. Commun., 2017,53, 5193-5195

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Transformation of the ionic liquid [EMIM][B(CN)4] into anionic and neutral lanthanum tetracyanoborate coordination polymers by ionothermal reactions

S. H. Zottnick, M. Finze and K. Müller-Buschbaum, Chem. Commun., 2017, 53, 5193 DOI: 10.1039/C7CC01378G

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