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Issue 28, 2017
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Entropic electrolytes for anodic cycloadditions of unactivated alkene nucleophiles

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Abstract

Unactivated alkenes were previously found to be effective carbon nucleophiles for anodic cycloadditions in lithium perchlorate/nitromethane electrolyte solution. Herein, 7Li NMR analysis and calorimetric studies clearly illustrate that the entropic effect is essential for these anodic cycloadditions, which has led to the successful screening of novel effective electrolytes.

Graphical abstract: Entropic electrolytes for anodic cycloadditions of unactivated alkene nucleophiles

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Article information


Submitted
24 Jan 2017
Accepted
14 Mar 2017
First published
14 Mar 2017

Chem. Commun., 2017,53, 3960-3963
Article type
Communication

Entropic electrolytes for anodic cycloadditions of unactivated alkene nucleophiles

Y. Imada, Y. Yamaguchi, N. Shida, Y. Okada and K. Chiba, Chem. Commun., 2017, 53, 3960
DOI: 10.1039/C7CC00664K

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