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Issue 26, 2017
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Interplaying anions in a supramolecular metallohydrogel to form metal organic frameworks

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Abstract

The remarkable effect of anions on the transition from supramolecular gels to crystalline phases has been described. An amino acid-based metallohydrogel was transformed into different metal–organic frameworks through the selective picking of anions. The metallohydrogel and the resulting metal–organic frameworks (MOFs) were thoroughly characterized. The results demonstrated controlled access over the binding of a particular anion to selectively form a particular MOF.

Graphical abstract: Interplaying anions in a supramolecular metallohydrogel to form metal organic frameworks

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Article information


Submitted
20 Jan 2017
Accepted
28 Feb 2017
First published
03 Mar 2017

Chem. Commun., 2017,53, 3705-3708
Article type
Communication

Interplaying anions in a supramolecular metallohydrogel to form metal organic frameworks

S. Karak, S. Kumar, S. Bera, D. D. Díaz, S. Banerjee, K. Vanka and R. Banerjee, Chem. Commun., 2017, 53, 3705
DOI: 10.1039/C7CC00539C

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