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Issue 18, 2017
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Mn(IV) and Mn(V)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand

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Abstract

The electron-rich pincer ligand 1 has been synthesized and chelated to manganese. The octahedral Mn(IV) bis(diiminosemiquinonate) and Mn(V) (diiminobenzoquinone) (diiminosemiquinonate) radicals were structurally characterized.

Graphical abstract: Mn(iv) and Mn(v)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand

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Publication details

The article was received on 19 Jan 2017, accepted on 09 Feb 2017 and first published on 10 Feb 2017


Article type: Communication
DOI: 10.1039/C7CC00516D
Citation: Chem. Commun., 2017,53, 2764-2767

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    Mn(IV) and Mn(V)-radical species supported by the redox non-innocent bis(2-amino-3,5-di-tert-butylphenyl)amine pincer ligand

    N. Leconte, J. Moutet, K. Herasymchuk, R. M. Clarke, C. Philouze, D. Luneau, T. Storr and F. Thomas, Chem. Commun., 2017, 53, 2764
    DOI: 10.1039/C7CC00516D

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